The detection of post-monsoon tropospheric ozone variability over south Asia using IASI data

The ozone (O<sub>3</sub>) variability over south Asia during the 2008 post-monsoon season has been assessed using measurements from the MetOP-A/IASI instrument and O<sub>3</sub> profiles retrieved with the SOftware for a Fast Retrieval of IASI Data (SOFRID). The information content study and error analyses carried out in this paper show that IASI Level 1 data can be used to retrieve tropospheric O<sub>3</sub> columns (TOC, surface-225 hPa) and UTLS columns (225–70 hPa) with errors smaller than 20%. Validation with global radiosonde O<sub>3</sub> profiles obtained during a period of 6 months show the excellent agreement between IASI and radiosonde for the UTLS with correlation coefficient <i>R</i> > 0.91 and good agreement in the troposphere with correlation coefficient <i>R</i> > 0.74. For both the UTLS and the troposphere Relative Standard Deviations (RSD) are lower than 23%. Comparison with in-situ measurements from the MOZAIC program around Hyderabad demonstrates that IASI is able to capture the TOC inter and intra-seasonal variability in central India. Nevertheless, the agreement is mitigated by the fact that the smoothing of the true O<sub>3</sub> profiles by the retrieval results in a reduction of the TOC variability detected by IASI relative to the variability observed by in situ instruments. The post-monsoon temporal variability of the vertical profile of O<sub>3</sub> around Hyderabad has been investigated with MOZAIC observations. These observations from airborne instruments show that tropospheric O<sub>3</sub> is steadily elevated during most of the studied period with the exception of two sharp drops following the crossing of tropical storms over India. Lagrangian simulations with the FLEXPART model indicate that elevated O<sub>3</sub> concentrations in the middle troposphere near Hyderabad are associated with the transport of UTLS air-masses that have followed the Subtropical Westerly Jet (SWJ) and subsided over northern India together with boundary layer polluted air-masses transported from the Indo-gangetic plain by the north-easterly trades. Low O<sub>3</sub> concentrations result from the uplift and westward transport of pristine air-masses from the marine boundary layer of the Bay of Bengal by tropical storms. In order to extend the analysis of tropospheric O<sub>3</sub> variability to the whole of south Asia, we have used IASI-SOFRID O<sub>3</sub> data. We show that IASI O<sub>3</sub> data around Hyderabad were able to capture the fast variability revealed by MOZAIC. Furthermore, their spatio-temporal coverage demonstrates that the behaviour of tropospheric O<sub>3</sub> observed near Hyderabad extended over most of central and south India and part of the Bay of Bengal. This result highlights the ability of the IASI sensor to capture fast changes in chemical composition related to dramatic tropical weather conditions

Combined assimilation of IASI and MLS observations to constrain tropospheric and stratospheric ozone in a global chemical transport model

Accurate and temporally resolved fields of free-troposphere ozone are of major importance to quantify the intercontinental transport of pollution and the ozone radiative forcing. We consider a global chemical transport model (MOdèle de Chimie Atmosphérique à Grande Échelle, MOCAGE) in combination with a linear ozone chemistry scheme to examine the impact of assimilating observations from the Microwave Limb Sounder (MLS) and the Infrared Atmospheric Sounding Interferometer (IASI). The assimilation of the two instruments is performed by means of a variational algorithm (4D-VAR) and allows to constrain stratospheric and tropospheric ozone simultaneously. The analysis is first computed for the months of August and November 2008 and validated against ozonesonde measurements to verify the presence of observations and model biases. Furthermore, a longer analysis of 6 months (July–December 2008) showed that the combined assimilation of MLS and IASI is able to globally reduce the uncertainty (root mean square error, RMSE) of the modeled ozone columns from 30 to 15% in the upper troposphere/lower stratosphere (UTLS, 70–225 hPa). The assimilation of IASI tropospheric ozone observations (1000–225 hPa columns, TOC – tropospheric O₃ column) decreases the RMSE of the model from 40 to 20% in the tropics (30° S–30° N), whereas it is not effective at higher latitudes. Results are confirmed by a comparison with additional ozone data sets like the Measurements of OZone and wAter vapour by aIrbus in-service airCraft (MOZAIC) data, the Ozone Monitoring Instrument (OMI) total ozone columns and several high-altitude surface measurements. Finally, the analysis is found to be insensitive to the assimilation parameters. We conclude that the combination of a simplified ozone chemistry scheme with frequent satellite observations is a valuable tool for the long-term analysis of stratospheric and free-tropospheric ozone

Upper-tropospheric CO and O₃ budget during the Asian summer monsoon

During the Asian summer monsoon, the circulation in the upper troposphere/lower stratosphere (UTLS) is dominated by the Asian monsoon anticyclone (AMA). Pollutants convectively uplifted to the upper troposphere are trapped within this anticyclonic circulation that extends from the Pacific Ocean to the Eastern Mediterranean basin. Among the uplifted pollutants are ozone (O₃) and its precursors, such as carbon monoxide (CO) and nitrogen oxides (NO_<i>x</i>). Many studies based on global modeling and satellite data have documented the source regions and transport pathways of primary pollutants (CO, HCN) into the AMA. Here, we aim to quantify the O₃ budget by taking into consideration anthropogenic and natural sources. We first use CO and O₃ data from the MetOp-A/IASI sensor to document their tropospheric distributions over Asia, taking advantage of the useful information they provide on the vertical dimension. These satellite data are used together with MOZAIC tropospheric profiles recorded in India to validate the distributions simulated by the global GEOS-Chem chemistry transport model. Over the Asian region, UTLS monthly CO and O₃ distributions from IASI and GEOS-Chem display the same large-scale features. UTLS CO columns from GEOS-Chem are in agreement with IASI, with a low bias of 11 ± 9 % and a correlation coefficient of 0.70. For O₃, the model underestimates IASI UTLS columns over Asia by 14 ± 26 % but the correlation between both is high (0.94). GEOS-Chem is further used to quantify the CO and O₃ budget through sensitivity simulations. For CO, these simulations confirm that South Asian anthropogenic emissions have a more important impact on enhanced concentrations within the AMA (∼  25 ppbv) than East Asian emissions (∼  10 ppbv). The correlation between enhanced emissions over the Indo-Gangetic Plain and monsoon deep convection is responsible for this larger impact. Consistently, South Asian anthropogenic NO_<i>x</i> emissions also play a larger role in producing O₃ within the AMA (∼  8 ppbv) than East Asian emissions (∼  5 ppbv), but Asian lightning-produced NO_<i>x</i> is responsible for the largest O₃ production (10–14 ppbv). Stratosphere-to-troposphere exchanges are also important in transporting O₃ in the upper part of the AMA

The detection of post-monsoon tropospheric ozone variability over south Asia using IASI data

International audienceThe ozone (O3) variability over south Asia during the 2008 post-monsoon season has been assessed using measurements from the MetOP-A/IASI instrument and O3 profiles retrieved with the SOftware for a Fast Retrieval of IASI Data (SOFRID). The information content study and error analyses carried out in this paper show that IASI Level 1 data can be used to retrieve tropospheric O3 columns (TOC, surface-225 hPa) and UTLS columns (225-70 hPa) with errors smaller than 20%. Validation with global radiosonde O3 profiles obtained during a period of 6 months show the excellent agreement between IASI and radiosonde for the UTLS with correlation coefficient R > 0.91 and good agreement in the troposphere with correlation coefficient R > 0.74. For both the UTLS and the troposphere Relative Standard Deviations (RSD) are lower than 23%. Comparison with in-situ measurements from the MOZAIC program around Hyderabad demonstrates that IASI is able to capture the TOC inter and intra-seasonal variability in central India. Nevertheless, the agreement is mitigated by the fact that the smoothing of the true O3 profiles by the retrieval results in a reduction of the TOC variability detected by IASI relative to the variability observed by in situ instruments. The post-monsoon temporal variability of the vertical profile of O3 around Hyderabad has been investigated with MOZAIC observations. These observations from airborne instruments show that tropospheric O3 is steadily elevated during most of the studied period with the exception of two sharp drops following the crossing of tropical storms over India. Lagrangian simulations with the FLEXPART model indicate that elevated O3 concentrations in the middle troposphere near Hyderabad are associated with the transport of UTLS air-masses that have followed the Subtropical Westerly Jet (SWJ) and subsided over northern India together with boundary layer polluted air-masses transported from the Indo-gangetic plain by the north-easterly trades. Low O3 concentrations result from the uplift and westward transport of pristine air-masses from the marine boundary layer of the Bay of Bengal by tropical storms. In order to extend the analysis of tropospheric O3 variability to the whole of south Asia, we have used IASI-SOFRID O3 data. We show that IASI O3 data around Hyderabad were able to capture the fast variability revealed by MOZAIC. Furthermore, their spatio-temporal coverage demonstrates that the behaviour of tropospheric O3 observed near Hyderabad extended over most of central and south India and part of the Bay of Bengal. This result highlights the ability of the IASI sensor to capture fast changes in chemical composition related to dramatic tropical weather conditions

Measurements of mid-stratospheric formaldehyde from the Odin/SMR instrument

International audienceMeasurements of mid-stratospheric formaldehyde (H2CO) have been obtained from the limb-viewing sub-millimeter radiometer (SMR) instrument aboard the Odin satellite. The analysis is based upon the only weak (808→707) rotational transition line of H2CO that can be measured by Odin/SMR at 576.7083150 GHz in the band dedicated to the measurement of carbon monoxide (CO). The signal-to-noise ratio is increased by averaging about 1000 spectra within 2-km width vertical layers in the stratosphere over periods from 1 to 7 days and within 3 latitude bands: Southern Hemisphere (90°S–45°S), tropics (30°S–30°N), and Northern Hemisphere (45°N–90°N). The faint H2CO line can then be retrieved using the standard scientific ground-segment developed for the Odin/SMR measurements. The mid-stratospheric H2CO shows maxima in the tropics for every period considered (January 2006, February 2005, March 2005, and September 2005). The spring-time extra-tropical mid-stratospheric H2CO is more intense than the fall-time extra-tropical amounts. The simulations from the three-dimensional chemical-transport model Reprobus satisfactorily show these general features